Stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. Propagation of stress corrosion cracks in pipeline. Effect of microstructure and crystallography on sulfide stress. Laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stress corrosion cracking. Transgranular cracking is a key characteristic of chloride induced stress corrosion cracking in austenitic stainless steels. Stress corrosion cracking odonnell consulting engineers, inc. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Ian sutton, in plant design and operations second edition, 2017. In addition, some intergranular fracture areas were also perceptible on.
In stress corrosion cracking, its first cousin, the corrosion process, generally pitting, must start to get the hydrogen generation started. Prolonged exposure to sour gas can lead to hydrogen damage, sulfide stress cracking, andor stress corrosion cracking in ferrous alloys. Standard test method laboratory testing of metals for. Intergranular cracking is the cracking or fracture that occurs at and along the grain boundaries of a metal metals handbook, volume 11. Intergranular stress corrosion cracking igscc of bwr internal components has been identified as a technical issue of concern by both the nrc staff and the industry. This is, of course, a very complex question for a forum like this. Pdf sulfide stress corrosion cracking and hydrogen. It is characterized by triple points, rockcandy or faceted appearance when the fracture is analyzed through sem metals handbook, volume 12. Sulfide stress cracking ssc vs hydrogen induced cracking. Stress relief cracking occurs only in metals that can precipitationharden during such elevatedtemperature exposure. H 2 s can cause corrosion of stainless steels such as 316 and 410 stainless in the form of sulfide stress cracking. The required tensile stresses may be in the form of directly applied stresses or in the form of residual stresses, see an example of scc of an aircraft component. The effects of sulfide stress cracking on the mechanical properties. Although the scc was initiated by an intergranular mechanism, the crack.
Intergranular cracking of oil field tubular components. This phenomenon is generally termed sulfide stress cracking ssc when operating at room temperature and stress corrosion cracking scc when operating at higher temperatures. When placed in proximity to tensile stresses, embrittlement and the beginnings of brittle fracture may occur. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. Damage due to hydrogen embrittlement and stress corrosion. Intergranular stress corrosion cracking igscc cracks propagate along the grain boundaries. Thus, catastrophic failure can occur without significant deformation or obvious deterioration of the component. It can occur when carbonsteel equipment becomes exposed to wet h 2 s service environments, and it can come in several different forms. For this reason, along with toxicity risks of hydrogen sulfide gas, it is essential that water muds be kept entirely free of soluble sulfides and especially hydrogen sulfide at low ph. Sulfide stress cracking resistant drill pipe addresses h2s challenges. Oct 24, 20 sulfide stress cracking resistant drill pipe addresses h2s challenges. Intergranular corrosion induced by environmental stresses is termed stress corrosion cracking.
Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Transgranular stress corrosion cracking tgscc is the same as igscc, but the grain boundaries are not preferentially attacked 1, 2. Sulfide stress cracking ssc resistance of casing steels with different alloying chemistries i. Sulfide stress cracking ssc occurs at locations where atomic hydrogen is able to diffuse at sites of high internal stress, such as grain boundaries, inclusions and regions of triaxial stress at notches. Or a structure under static tensile stress, much below the yield stress, in contact with corrosive environment may fail due to scc. Sulfide stress cracking is also environmentally produced so you have a delay until the sulfide environment causes hydrogen entry into the metal. In this chapter the terms eac and scc are generally interchangeable. Sulfide stress cracking an overview sciencedirect topics. Mechanical and metallurgical failure mechanisms flashcards.
Sulfide stress cracking ssc is one of the detrimental types of corrosion which happens in sour environment. Hydrogen sulfide is a colorless, very poisonous, flammable gas with the characteristic foul odor of rotten eggs. Sulfide stress cracking ssc of high strength, low alloy steel is a phenomenon of particular concern to the oil and gas industry 3. There are maximum acceptable h 2 s concentration limits in sale quality oil and gas, which require. The presence of flaws that concentrate stress or crevices that alter. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature.
Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking. Stress corrosion cracking or season cracking occurs only in the simultaneous presence of a sufficiently high tensile stress and a specific corrosive environment. Material damage due to hydrogen embrittlement and stress corrosion cracking can be classed as cases. Transgranular corrosion is also known as intragranular corrosion and transcrystalline corrosion. H3 in the attached figures is the steam line break, since the lifting forces generated may be sufficient to elevate the top guide, possibly affecting lateral support of the. Transgranular stress corrosion cracking tgscc is the same as igscc, but. For brasses the environment involved is usually one containing ammonia or closely related substances such as amines, but atmospheres containing between 0. Ssc resistance in terms of rah2sraair and time to failure was found to decrease with increase of material strength. Subsequent improvements in the metallurgy of steels for highpressure gas and oil wells and improved selection methods for highstrength alloys have been based on laboratory test methods. Cracking can result from creep damage, from fatigue cracking from sulfide stress cracking or hydrogen disbonding. The list of acronyms and abbreviations related to ssc sulfide stress cracking. Intergranular corrosion igc can seriously weaken the bonding force between crystal grains and the mechanical strength of metals and alloys would be markedly.
Wet h 2 s corrosion can be a particularly dangerous form of corrosion because damage caused by it takes place on the interior of. Jan 22, 20 stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. Vargas pm, wastberg s and woollin p, stress based design guidelines for hydrogen induced stress cracking hisc avoidance in duplex materials, proc conf omae 200979504. Intergranular stress corrosion cracking of welded steel twi. Sulphide stress cracking is prevented by minimising the hardness and strength. Efc publication 17, 2nd edition, corrosion resistant alloys for oil and gas production. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Sulfide stress cracking ssc cracking usually is designated as either intergranular intercrystalline or transgranular transcrystalline. In a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. It addresses hydrogeninduced cracking of steel weldments, sensitization and subsequent intergranular corrosion of stainless steel weldments, sulfide stress cracking of pipeline steel weldments, microbiologically induced corrosion of weldments, and stress corrosion cracking of weldments. Stress corrosion cracking odonnell consulting engineers. Sulphide stress corrosion cracking sulphide stress cracking sscc has special importance in gas and oil industry, as the materials being processed there natural gas and crude oil often contain considerable amount of hydrogen sulphide. This phenomenon is generally termed sulfide stress cracking ssc 1 when operating at room temperature and stress corrosion cracking scc1 when operating at higher temperatures. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation.
Transgranular stress corrosion cracking tgscc cracks run through the individual grains. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Corrosionpedia what is sulfide stress cracking ssc. Hydrogen induced cracking of subsea duplex stainless steel twi. Stress corrosion cracking scc the impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Pdf sulfide stress corrosion cracking and hydrogen induced. Mechanisms of stresscorrosion cracking asm international. Sulfide stress cracking, a form of hydrogen embrittlement, first became a serious problem in the oil industry in 1951.
Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Sulfide stress cracking behavior of a martensitic steel controlled by. Intergranular stress corrosion cracking of core shrouds. Intergranular stress corrosion cracking an overview. H 2 s can cause sulfide stress cracking of stainless steels. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. The embrittlement induced by ssc causes failure of steel at a stress level, which is significantly lower than its yield strength. By detailed metallurgical tests it was proven that the failure had been brought about by stress corrosion cracking. Hydrogen sulfide, being very toxic to people and wild life and polluting to the environment, is also very. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. H2s partial pressure, 1 mpa and co2 partial pressure, 1 mpa.
Alloys which are commercially available and those which have modified metallurgical structures and. Ssc quickly diminishes performance of downhole tubulars. Lippold j and alexandrov b, phase transformations during welding and postweld heat treatment of a 12cr6. Variation and degradation of p110 casing steel mechanical properties, due to sulfide stress cracking ssc in sour environments, was investigated using te. Reliability of dissimilar metal welds subjected to sulfide. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. Sulfide stress cracking how is sulfide stress cracking. Sulphide stress cracking sscc has special importance in gas and oil industry, as the materials being processed there natural gas and crude oil often contain considerable amount of hydrogen sulphide.
Intergranular stress corrosion cracking igscc is stress corrosion cracking where the grain boundaries of a susceptible material are cracked due to stress and an agressive environment. Laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h2s environments. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Occasionally, both types of cracking are observed in a failure. Temperature is a significant environmental factor affecting cracking. Stress corrosion cracking can proceed in one of two ways. When the hinduced stress concentration exceeded the atomic binding force. Intergranular cracking is also known as intergranular corrosion, intergranular corrosion cracking, intergranular stress corrosion cracking igscc, intercrystalline corrosion, interdendritic corrosion or intergranular attack. The threshold stresses to cause cracking are commonly below the yield stress of the material.
Sulfide stress cracking resistant metallic materials for oilfield equipment contents 1. Stresscorrosion cracking scc is a term used to describe. Woollin p, postweld heat treatment to avoid intergranular stress corrosion cracking of supermartensitic stainless steels, proc conf stainless steel world 2005, kci publishing, paper no. Both intergranular and transgranular stress corrosion cracking are.
Material considerations when working with hydrogen 3. This form of cracking, which typically changes from transgranular 1 to intergranular 2 with increasing. Prior to the discovery of this new form of cracking, scc was thought to be a relatively wellunderstood, intergranular. Nace tm01772016 laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h2s environments. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Aug 14, 20 impact toughness of the casing decreased significantly and intergranular cracking occurred when specimens were maintained at a high stress level of 85%. Why is chloride stress corrosion cracking transgranular. Standard material requirements sulfide stress cracking. Producing wet sour gas presents some of the toughest technical challenges in the oil and gas business. However, the time required for crack initia tion is strongly dependent on a wide variety of pa rameters, such as surface finish. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be. Sulfide stress cracking of highstrength steels is a problem in handling sour hydrogen sulfide containing crude oil or natural gas.
Tib and mncrmo was evaluated using constant load tensile test and slow strain rate test in nacetm0177 environment. In recognition of the variation with temperature and with different materials this phenomenon is here called environmental cracking ec. In that article, we concluded that while localized corrosion appears to be a prerequisite for anodic eac modes such as stress corrosion cracking scc, hydrogenassisted eac mechanisms like hydrogen stress cracking hsc are exacerbated at cathodic potentials. Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. These tests were carried out on specimens, which were pretreated under the following conditions for 168 hours. Variation and degradation of p110 casing steel mechanical properties, due to sulfide stress cracking ssc in sour environments, was investigated using tensile and impact tests. This standard addresses the testing of metals for resistance to cracking failure under the combined action of tensile stress and corrosion in aqueous environments containing hydrogen sulfide h 2 s. Cracking of dissimilar metal welds occurs in the ferritic cs or low alloy side of a weld between an austenitic 300ss or nialloy and a ferritic material operating at high tmeperature. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. An industry value that has been developed is nace mr01. The effects of sulfide stress cracking on the mechanical.
Is sulfide stress cracking an anodic or a cathodic process. Sulphide stress corrosion cracking sscc laboratory. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Inter granular corrosion can be detected by ultrasonic and eddy current methods. Sulfide stress cracking susceptibility tests were conducted as per nace tm 017796 method a, the tests were conducted at different applied loads 60%, 80%, and 110% of the yield strength values of the welded samples. Although the scc was initiated by an intergranular mechanism, the crack propagation was transgranular. Wet hydrogen sulfide h2s cracking inspectioneering. Other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Standard material requirements sulfide stress cracking resistant metallic materials for oilfield equipment contents 1. Laboratory testing of metals for resistance to sulfide.
Sulfide stress cracking ssc also known as sour gas cracking sour gas. Intergranular cracks follow the grain boundaries in the metal. Hydrogen sulfide stress corrosion cracking in materials. Intergranular cracking is a form of corrosive attack that progresses preferentially along grain boundaries. A typical indication for this kind of damage is the branched cracks of fig. This is a complex topic, other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Sulfide stress cracking of pipelinecase history onepetro. Sscc is a low temperature temperature where water is liquid effect of h2s in an aqueous environment and sulfidation is the term used for the. Sulfide stress crackingresistant drill pipe addresses h2s.
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